This is U. S. Patent 4000998
                 Spontaneously-formed nepheline-carnegieite glass-ceramics

Abstract

The instant invention relates to the manufacture of articles demonstrating the physical properties and internal microstructure of glass-ceramic bodies but which can be formed spontaneously from molten glass. Thus, the heat treatment of a precursor glass body, such as is required in the production of conventional glass-ceramic articles to cause the crystallization in situ thereof, is avoided. More particularly, this invention relates to the manufacture of highly crystalline glass-ceramic articles having compositions within the Na.sub.2 O-Al.sub.2 O.sub.3 -SiO.sub.2 field, wherein carnegieite and/or nepheline solid solution crystals constitute the predominant crystal phase, which can be formed spontaneously from a molten glass batch.























Description


U.S. applications Ser. Nos. 559,725 and 559,787, filed concurrently herewith by David G. Grossman, and U.S. aplication Ser. No. 559,732, filed concurrently herewith by J. E. Flannery and D. R. Wexell, disclose the production of spontaneously formed glass-ceramic articles wherein a fluormica comprises the primary crystal phase. U.S. applications Ser. Nos. 559,726, 559,789, and 559,727, also filed concurrently herewith by David G. Grossman, disclose the production of spontaneously formed glass-ceramic articles wherein celsian, mullite, and beta-spodumene solid solution, respectively, constitutes the predominant crystal phase. U.S. application Ser. No. 559,786, filed concurrently herewith by George H. Beall, discloses the manufacture of spontaneously formed glass-ceramic articles wherein alpha-quartz solid solution constitutes the predominant crystal phase. U.S. application Ser. No. 559,788, also filed concurrently herewith by G. H. Beall, P. E. Balszyk, and W. T. Brydges, III, describes the manufacture of spontaneously formed glass-ceramic articles wherein beta-spodumene solid solution constitutes the principal crystal phase. Finally, U.S. Application Ser. No. 559,731, filed concurrently herewith by the present applicant, discusses the production of spontaneously formed glass-ceramic articles wherein BaO and/or SrO-Fe.sub.2 O.sub.3 -SiO.sub.2 solid solution comprises the predominant crystal phase.

































































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